Voltametric Analysis of Tris(aryliminocarboxylato)chromium(III) Complexes
Abstract
Homoleptic chromium complexes bearing o-arylimino carboxylate ligands have been prepared. These complexes have been subjected to voltametric analysis and measured potentials have been correlated to their varying substituent effects. Complexes bearing ancillary aryl –CN, –NO2, –COOMe, –F, –Cl, –OMe and –NMe2 groups displayed measurable potentials. Preferred geometric isomers for each structure were utilized to model both oxidation and reduction energies using chromium(III) picolinate as a reference.
College
College of Science & Engineering
Department
Chemistry
Campus
Winona
First Advisor/Mentor
Jennifer Zemke
Second Advisor/Mentor
Joseph West
Location
Ballroom - Kryzsko Commons
Start Date
April 2024
End Date
April 2024
Presentation Type
Poster Session
Format of Presentation or Performance
In-Person
Session
2a=1pm-2pm
Poster Number
11
Voltametric Analysis of Tris(aryliminocarboxylato)chromium(III) Complexes
Ballroom - Kryzsko Commons
Homoleptic chromium complexes bearing o-arylimino carboxylate ligands have been prepared. These complexes have been subjected to voltametric analysis and measured potentials have been correlated to their varying substituent effects. Complexes bearing ancillary aryl –CN, –NO2, –COOMe, –F, –Cl, –OMe and –NMe2 groups displayed measurable potentials. Preferred geometric isomers for each structure were utilized to model both oxidation and reduction energies using chromium(III) picolinate as a reference.
