Development of a gas chromatographic method for the determination of alcohols in hand sanitizers

Presenter(s)

Alexander Gibbs

Abstract

The purpose of this research was to determine which alcohols are present in commonly found hand sanitizers and what their unknown concentrations are. In addition to determining the concentration of alcohol in hand sanitizer, the research performed was implemented as a new piece of curriculum in the instrumental analysis class. This research allowed for the design of a lab that allows students to obtain hands on experience with the GC-FID while learning about its performance and capabilities. The GC-FID was used as the piece of analytical instrumentation for the determination of alcohol concentration in hand sanitizers. This test required the use of internal standards, calculations, dilutions, and proper instrument analysis. The GC-FID was chosen for this research due to its ability to accurately measure highly volatile chemicals at extreme precision. Each alcohol was initially tested alone with the internal standard to determine retention time and to give a known concentration value for an area under the curve. Many adjustments were made to the GC-FID method to obtain the most accurate values. The results show that both of the store-bought hand sanitizers do not meet FDA standards. The amount of ethanol measured in both samples was also less than what was listed on the hand sanitizer container. The Wish Peach Hand Sanitizer was measured at 46.6% ethanol concentration while the package said it contained 70% ethanol. This leads to a percent error of 50.21%. The Symmetry Hand Sanitizer had much more accurate results, the observed value was 59.08% and the package had a concentration of 62%. This yields a percent error of 4.94%. This signifies the accuracy of the method that is being tested. The large reason for error in the Wish Hand Sanitizer would be due to the consistency of the sanitizer. The micropipette struggled to pick up the hand sanitizer making it difficult to accurately quantify.

College

College of Science & Engineering

Department

Chemistry

Campus

Winona

First Advisor/Mentor

Jeanne Franz

Start Date

4-24-2025 1:00 PM

End Date

4-24-2025 2:00 PM

Presentation Type

Poster Session

Format of Presentation or Performance

In-Person

Session

2a=1pm-2pm

Poster Number

17

Comments

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Apr 24th, 1:00 PM Apr 24th, 2:00 PM

Development of a gas chromatographic method for the determination of alcohols in hand sanitizers

The purpose of this research was to determine which alcohols are present in commonly found hand sanitizers and what their unknown concentrations are. In addition to determining the concentration of alcohol in hand sanitizer, the research performed was implemented as a new piece of curriculum in the instrumental analysis class. This research allowed for the design of a lab that allows students to obtain hands on experience with the GC-FID while learning about its performance and capabilities. The GC-FID was used as the piece of analytical instrumentation for the determination of alcohol concentration in hand sanitizers. This test required the use of internal standards, calculations, dilutions, and proper instrument analysis. The GC-FID was chosen for this research due to its ability to accurately measure highly volatile chemicals at extreme precision. Each alcohol was initially tested alone with the internal standard to determine retention time and to give a known concentration value for an area under the curve. Many adjustments were made to the GC-FID method to obtain the most accurate values. The results show that both of the store-bought hand sanitizers do not meet FDA standards. The amount of ethanol measured in both samples was also less than what was listed on the hand sanitizer container. The Wish Peach Hand Sanitizer was measured at 46.6% ethanol concentration while the package said it contained 70% ethanol. This leads to a percent error of 50.21%. The Symmetry Hand Sanitizer had much more accurate results, the observed value was 59.08% and the package had a concentration of 62%. This yields a percent error of 4.94%. This signifies the accuracy of the method that is being tested. The large reason for error in the Wish Hand Sanitizer would be due to the consistency of the sanitizer. The micropipette struggled to pick up the hand sanitizer making it difficult to accurately quantify.